Acyl, alkyl, and aryl complexes of iridium from acid chlorides
✍ Scribed by Kubota, Mitsuru; Blake, Daniel M.
- Book ID
- 126402978
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 731 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Acid chlorides react with Sm12 to give a-diketones.Various experiments show that theinitially formed acyl radical is rapidly transformed into an acyl anion which is thus generated byquite an unusual route. This species acylates acid chlorides, aldehydes and ketones in situ to give a-diketones and a-
The double C H bond activation of ethers that have an alkyl terminus, RCH 2 OR (R = alkyl, aryl), is a useful route to heteroatom-stabilized iridium carbenes, Ir = C(R)OR . An overview of our recent work in this field, using Ir(III) fragments stabilized by hydrotris(pyrazolyl)borate ligands, is pres