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Activity of [Sm(C5Me5)3] in Ethylene Polymerization and Synthesis of [U (C5Me5)3], the First Tris(pentamethylcyclopentadienyl) 5f-Element Complex

✍ Scribed by Prof. William J. Evans; Kevin J. Forrestal; Dr. Joseph W. Ziller

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
383 KB
Volume
36
Category
Article
ISSN
0044-8249

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Formal Three-Electron Reduction by an f-Element Complex: Formation of [{(C5Me5)(C8H8)U}2(C8H8)] from Cyclooctatetraene and [(C5Me5)3U]
✍ William J. Evans; Gregory W. Nyce; Joseph W. Ziller 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 100 KB 👁 1 views

Reduction reactions involving more than two electrons are not common for metal complexes containing just one metal. In f-element chemistry, multielectron reductions from monometallic species are particularly rare since the common lowvalent ions Th III , U III , Eu II , Yb II , Sm II , and Tm II ty