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A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C5Me5)U{μ-η5:η1:η1-C5Me3(CH2)2}(μ-H)2U(C5Me5)2]

✍ Scribed by William J. Evans; Kevin A. Miller; Antonio G. DiPasquale; Arnold L. Rheingold; Timothy J. Stewart; Robert Bau


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
339 KB
Volume
47
Category
Article
ISSN
0044-8249

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✍ Herbert Schumann; Markus R. Keitsch; Jörg Demtschuk; Stefan Mühle 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 171 KB 👁 2 views

The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4