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Activity Coefficients of 2:1 Complex Ion Electrolytes: Nitropentaamminecobalt(III) Chloride, Chloropentaamminecobalt(III) Perchlorate, and Fluoropentaamminecobalt(III) Chloride

✍ Scribed by Masterton, W. L.; Scola, Jacqueline A.


Book ID
115523866
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
298 KB
Volume
68
Category
Article
ISSN
0022-3654

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Aquation of chloropentaamminecobalt(III)
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The equilibrium quotients for the formation of Co(NH3) SCl2+ from Co(NH3) 50Hz3+ and CI1were 3.74 f 0.25 M-' and 6.07 f 0.54 M-' at 45.OoC in 10: 1 mole ratio water: dimethyl sulfoxide and in 25 w/w yo aqueous ethanol, respectively, and those for the formation ofthe ion pair C O ( N H ~) ~O H ~~+ .