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The racemization of complex ions on activated carbon—II: The racemization of d-tris(ethylenediamine)cobalt(III) chloride and other complexes

✍ Scribed by W.C. Erdman; H.E. Swift; B.E. Douglas

Book ID: 118904750
Publisher: Elsevier Science
Year: 1962
Weight: 427 KB
Volume: 24
Category: Article
ISSN: 0022-1902
DOI: 10.1016/0022-1902(62)80144-4

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Aquation rates for cis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1 .O M HNOz at 50-80°C. Kinetic parameters are (in the above order of A) 1O7k29s (sec-I), 7.4, 5.7, 1.3, 9.7; E, (kJ/mole), 103, 101, 130, 112; lo