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Active sites on ZrO2 for the formation of isobutene from CO and H2

✍ Scribed by Ken-ichi Maruya; Teruaki Komiya; Tomoki Hayakawa; Lianhai Lu; Masatomo Yashima

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
104 KB
Volume
159
Category
Article
ISSN
1381-1169

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✍ Ken-ichi Maruya; Akihiro Takasawa; Takashi Haraoka; Kazunari Domen; Takaharu Oni πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 737 KB

The role of metboxide species in selective formation of isobutene from CO and H, over ZrO, was investigated by means of 13C tracer method. Analysis of 13C-13C coupling in the formed isobutene showed that "CO hydrogenation over ZrO, pretreated with 13C0 and H, formed '2CH,='3C('2CH3)2, while j3C0 hyd