## Abstract Kinetic and thermodynamic investigations were performed for a mixed aqueous‐organic, 1:1 (v/v) water–1,4‐dioxane medium, which was found to be an efficient solvent for the interaction of a neutral dichlorotris(triphenylphosphine) ruthenium(II), RuCl~2~(PPh~3~)~3~ complex with carbon mon
Activation thermodynamics of the binding of carbon monoxide to horseradish peroxidase: Role of pressure, temperature and solvent
✍ Scribed by Claude Balny; Franck Travers
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 650 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0301-4622
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## Abstract By means of the negative solvatochromic betaine dyes 1a, b, the UV/Vis‐spectroscopically derived empirical solvent polarity parameter __E__~T~(30) for supercritical carbon dioxide (sc‐CO~2~) was determined in the temperature and pressure ranges 40–80°C and 150–550 bar, respectively.
The excess molar enthalpies H E m of five binary mixtures: (carbon dioxide + methanol, or ethanol, or N-methyl-2-pyrrolidone, or methyl cyanoacetate, or N-formyl morpholine), and one ternary mixture: [xCO2 + (1x){0.8085(CH2)4SO2 + 0.1915H2O}] were measured at the temperature T = 298.15 K and pressur