Activation parameters of supercritical and gas-phase β-pinene thermal isomerization
✍ Scribed by A. M. Chibiryaev; A. Yermakova; I. V. Kozhevnikov
- Book ID
- 110185470
- Publisher
- International Academic Publishing Co (Nauka/Interperiodica)
- Year
- 2011
- Tongue
- English
- Weight
- 365 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0036-0244
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The gas-phase thermal isomerization of hexachlorocyclopropane to hexachloropropene at 208-283OC is first order and unaffected by changes in the surface-to-volume ratio or by the addition of iodine, tetrachloroethylene, and oxygen. The first-order rate constants fit the Arrhenius equation log k(s-')
## Abstract The kinetics of the gas‐phase decomposition of 1,2‐epoxycyclohexane has been studied over the temperature range 680–740 K at pressures between 1.6 and 6 torr. Isomerization to cyclohexanone and 2‐cyclohexen‐1‐ol accounts for ca. 97% of the primary reaction products and occurs by first‐o