𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines

✍ Scribed by Vyas, Devendra J.; Fröhlich, Roland; Oestreich, Martin


Book ID
120244486
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
771 KB
Volume
13
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Catalytic Asymmetric Synthesis of α,α,α-
✍ Caroline Lauzon; Andre B. Charette 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Copper-Catalyzed 1,2-Addition of Nucleop
✍ Dr. Christian Kleeberg; Evgenia Feldmann; Eduard Hartmann; Devendra J. Vyas; Pro 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 303 KB

## Abstract Activation of the SiB inter‐element bond with copper(I) alkoxides produces copper‐based silicon nucleophiles that react readily with aldehydes to yield α‐silyl alcohols (that is, α‐hydroxysilanes) after hydrolysis. Two independent protocols were developed, one employing a well‐defined