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Activation of the reverse-Cope elimination by allylic oxygen functions: Syntheses of (−)-hygroline and (+)-pseudohygroline

✍ Scribed by David W. Knight; Rhys Salter

Book ID
104261914
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
230 KB
Volume
40
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Activation of the Reverse-Cope Elimination by Allylic Oxygen Functions: Syntheses of (-)-Hygroline and (+)-Pseudohygroline.
✍ David W. Knight; Rhys Salter 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Activation of the Reverse-Cope Elimination by Allylic Oxygen Functions: Syntheses of (-)-Hygroline and (+)-Pseudohygroline. -The reverse-Cope cyclization of the N-(4-alkenyl)hydroxylamine (I) is remarkably accelerated by the presence of the allylic oxygen providing the precursors (II) and (III) of (