Activation of silanes by Grubbs’ carbene
✍
Sarah V Maifeld; Reagan L Miller; Daesung Lee
📂
Article
📅
2002
🏛
Elsevier Science
🌐
French
⚖ 143 KB
This manuscript describes two catalytic methods for silyl ether synthesis using Grubbs' catalyst Cl 2 (PCy 3 ) 2 Ru CHPh. Silyl ethers are obtained from the reaction of a variety of silanes with alcohols by dehydrogenative condensation and by the hydrosilylation of carbonyl compounds. Both reactions