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Activation of Silanes by Grubbs′ Carbene Complex Cl2(PCy3)2Ru=CHPh: Dehydrogenative Condensation of Alcohols and Hydrosilylation of Carbonyls.

✍ Scribed by Sarah V. Maifeld; Reagan L. Miller; Daesung Lee


Book ID
101932036
Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
33
Category
Article
ISSN
0931-7597

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Activation of silanes by Grubbs’ carbene
✍ Sarah V Maifeld; Reagan L Miller; Daesung Lee 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 143 KB

This manuscript describes two catalytic methods for silyl ether synthesis using Grubbs' catalyst Cl 2 (PCy 3 ) 2 Ru CHPh. Silyl ethers are obtained from the reaction of a variety of silanes with alcohols by dehydrogenative condensation and by the hydrosilylation of carbonyl compounds. Both reactions