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Activation of organozinc reagents with t-Bu-P4 base for transition metal-free catalytic SN2′ reaction

✍ Scribed by Kobayashi, Koji; Ueno, Masahiro; Naka, Hiroshi; Kondo, Yoshinori


Book ID
120303084
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
119 KB
Volume
32
Category
Article
ISSN
1359-7345

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SN2′ Reaction of Organozinc Reagents Act
✍ Koji Kobayashi; Masahiro Ueno; Hiroshi Naka; Yoshinori Kondo 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 289 KB 👁 2 views

## Abstract The __t__Bu‐P4 base was found to be an excellent catalyst for the activation of organozinc reagents. The base was used to promote the S~N~2′ reaction of α,β‐unsaturated esters bearing a γ‐chloride in the reactions with various organozinc reagents in the presence of LiCl. The reactions p