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Activation of nitroaldol reactions by diethylzinc and amino alcohols or diamines as promoters

✍ Scribed by Günter Klein; Subramaniam Pandiaraju; Oliver Reiser


Book ID
104252035
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
98 KB
Volume
43
Category
Article
ISSN
0040-4039

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Synthesis of New Enantiopure γ-Amino Alcohols: Their Use as Catalysts in the Alkylation of Benzaldehyde by Diethylzinc. -Seven γ-amino alcohols are prepared by a convenient method based on 1,3-dipolar cycloaddition of the nitrone (I) to olefins. Among them the alcohols (VI) and (VIIa) are best cata