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Activation of molecular hydrogen by transition metal complexes 1. Autocatalysis in the hydrogenation of [PPh3Pd(OAc)2]2

✍ Scribed by A. S. Berenblyum; A. G. Knizhnik; S. L. Mund; I. I. Moiseev

Book ID
112440945
Publisher
Springer
Year
1978
Tongue
English
Weight
325 KB
Volume
27
Category
Article
ISSN
1573-9171

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Activation of Hydrogen by Palladium(0):
Activation of Hydrogen by Palladium(0): Formation of the Mononuclear Dihydride Complex trans-[Pd(H)2(IPr)(PCy3)]
✍ Serena Fantasia; Jonathan D. Egbert; Václav Jurčík; Catherine S. J. Cazin; Heiko 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 342 KB 👁 1 views

## Abstract **An even split**: In sharp contrast with the general behavior of Pd^0^ complexes, [Pd(IPr)(PCy~3~)] is able to activate the HH bond. The resulting __trans__‐[Pd(H)~2~(IPr)(PCy~3~)] is the first isolated mononuclear dihydride palladium compound. Its formation is supported by multinucle