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Activation of Dichloromethane by (Phosphane)orhodium(I) Complexes − X-ray Structure of [{(PEt3)2RhCl}2(μ-Cl)2(μ-CH2)]

✍ Scribed by Jean-Jacques Brunet; Xavier Couillens; Jean-Claude Daran; Ousmane Diallo; Christine Lepetit; Denis Neibecker

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 447 KB
Volume: 1998
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199803)1998:3<349::aid-ejic349>3.0.co;2-5

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✦ Synopsis

Dichloromethane reacts with dinuclear rhodium complexes diffraction study. The early stages of the reaction of [{(C 8 H 14 ) 2 Rh} 2 (µ-Cl) 2 ] with monophosphanes have been [{(PR 3 ) 2 Rh} 2 (µ-Cl) 2 ] to give the bridging-methylene complexes [{(PR 3 ) 2 RhCl} 2 (µ-Cl) 2 (µ-CH 2 )] (PR 3 = PEt 3 , PPh 2 Me). The monitored by 31 P NMR, evidencing chloride bridges cleavage and phosphane redistribution processes. structure of the PEt 3 complex has been established by X-ray

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