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Activation of carbon-carbon bond in the Mn-mediated cycloaddition reaction between disilacyclobutene and cyclohepta-1,3-diene

✍ Scribed by Chiang Hui-Jean; Liu Chao-Shiuan


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
200 KB
Volume
438
Category
Article
ISSN
0022-328X

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The photochemical 1,3-cycloaddition of c
✍ J. Kagan; J.T. Przybytek; B.E. Firth; S.P. Singh 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 203 KB

reoeived in UX for publication 13 IVovambsr 1972) When a benzene solution of either cis &-c) or trans 2-methyl-3-phenylglycidate 2-g) was irradiated in benzene under N 2 at 254 nm for 48 hrs., about 20% conversion to a complex mixture was observed. Silica gel chromatography afforded only one crystal