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Activation of a coordinated olefin toward nucleophilic attack

โœ Scribed by Eisenstein, Odile; Hoffmann, Roald


Book ID
126076277
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
240 KB
Volume
102
Category
Article
ISSN
0002-7863

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The activation of ฮท5-pyrrole complexes t
โœ M. Rakowski DuBois ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 329 KB

Pyrrole is a five-membered aromatic heterocycle in which the nitrogen lone pair is delocalized over the p system of the ring. As a result of this p electron rich character, it reacts readily with electrophiles, but is not susceptible to nucleophilic attack. The g5-coordination of pyrrole or of the p