Reactivity of distorted C5H5Fe(CO)2 (olefin) cations toward nucleophilic attack
β Scribed by Chang, T. C. T.; Foxman, Bruce M.; Rosenblum, M.; Stockman, C.
- Book ID
- 127268490
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 270 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Reaction of equimolar amounts of the ferriophosphaalkene P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature Ξ· 1 -coordination [(Ξ· 5 -C 5 Me 5 )(CO) 2 FeP=C(NMe 2 ) 2 ] (1a) or the ferrioarsaalkene [(Ξ· 5 -C 5 Me 5 )(CO) 2 FeAs=C(NMe 2 ) 2 ] (1b) wi
## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)βAs=C(NMe~2~)~2~ (11) afforded the novel Ξ·^2^β1βarsaallene complexes [Ξ·^2^β{__t__BuC(O)βAs=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi