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Action du sodium sur les phénylimino-éthers. I. Condensation des éthers phénylimino-benzoïques

✍ Scribed by Roland Jaunin; Gabriel Séchaud

Publisher
John Wiley and Sons
Year
1954
Tongue
German
Weight
410 KB
Volume
37
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The reaction of metallic sodium with phenyl, ethyl and benzyl phenyliminobenzoates has been investigated in an inert solvent. The main products are benzil‐dianil in case of the phenyl derivative, and benzanilide in case of the ethyl and benzyl derivatives. A free radical mechanism is postulated.

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Action du sodium sur les phénylimino-éth
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## Abstract Phenyl phenglimino‐o‐ and p‐toluates (II and III resp.) and phenyl phenylimino‐o‐methoxybenzoate (IV) react readily with metallic sodium in ethyl ether to produce mainly substituted benzildianils. Under the same conditions, phenyl phenyliniino‐p‐methoxybenzoate (V) fails to react apprec

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