The oxidative pyrolysis-atmospheric-pressure chemical ionization tandem mass spectrometry (Py-APCI MS/MS) of cyclotrimethylenetrinitramine (RDX) was investigated under various sample introduction conditions. Subambient (0.97 atm) as opposed to ambient (0.98 atm) pressure (1 atm = 101.325 kPa) facili
Acrylic compound characterization by oxidative pyrolysis, atmospheric pressure chemical ionization-tandem mass spectrometry
✍ Scribed by A.Peter Snyder
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 945 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0165-2370
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## Abstract Analytical pyrolysis‐atmospberic pressure ionization (Py‐API) tandem mass Spectrometry was used in the structure elucidation of the oxidalive and non‐oxidative thermal decomposition products of cyclotetramethylenetetranitramine (HMX). The [^15^NO~2~]‐, [^15^N~8~]‐ and [^2^H~8~]‐HMX isot