## Abstract Natural vegetable oils have been transformed in polymers following three main routes. The first is the direct polymerization through the double bonds of the fatty acid chain. The cationic copolymerization of soybean oil with styrene, divinylbenzene, and different amounts of styrenic mon
Acrylated vegetable oils as photocrosslinkable materials
✍ Scribed by Hélène Pelletier; Naceur Belgacem; Alessandro Gandini
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 142 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
Abstract
Acrylated soybean oil was irradiated in the near UV in the presence of free radical photoinitiators. Given the high substitution density of acrylic moieties, these oils responded very rapidly to the photopolymerization giving high yields of crosslinked materials within a few seconds. The activity of three photoinitiators was compared and the ensuing networks were characterized in terms of crosslink density through swelling measurements. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3218–3221, 2006
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