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Acido-Base Behavior of Hydroxamic Acids: Experimental and Ab Initio Studies on Hydroxyureas

✍ Scribed by Vrček, Ivana Vinković; Kos, Ivan; Weitner, Tin; Biruš, Mladen


Book ID
120445689
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
315 KB
Volume
112
Category
Article
ISSN
1089-5639

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The gas-phase equilibria NO;.(HONO), \_, + HONO# NO?(HONO), were measured in a high-prrssurc mass spcctromc-1cr between 240 and 350 I(. The following enthalpy channgcs were detcrmined:A.H:,1 = -31. aHy.2 = -21.6 and A$ 3 = -20.3 kcal/mol. These results are discussed in rchtion to the structures of N