Acidities of Nitrous and Nitric Acids
✍ Scribed by Otto Exner; Stanislav Böhm
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 71 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric
During the irradiation of phenol (1) with 15 N-enriched tetranitromethane in acetonitrile, and during the reaction of 1 with 15 N-enriched nitric acid and nitrous acid, emission due to the nitration products o-and p-nitrophenol (2a, 2b) is observed in the 15 N-NMR spectra. The CIDNP effects are buil
The dark reaction of NO, and HzO vapor in 1 atm of air was studied for the purpose of elucidating the recently discussed unknown radical source in smog chambers. Nitrous acid and nitric oxide were found to be formed by the reaction of NO2 and H2O in an evacuable and bakable smog chamber. No nitric a