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Acidities of Nitrous and Nitric Acids

✍ Scribed by Otto Exner; Stanislav Boehm


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Acidities of Nitrous and Nitric Acids
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Oxidation of benzyl alcohols by nitrous
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We have studied the oxidation of benzyl alcohols by nitrous and nitric acid in sulfuric acid media. The oxidation by nitrous acid is rapid and has an activation energy of 10.6 -t 0.8 kcal mol-'. A Hammett plot of logkp vs. u -is linear with a p value of -1.4. The oxidation by nitric acid in sulfuric

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During the irradiation of phenol (1) with 15 N-enriched tetranitromethane in acetonitrile, and during the reaction of 1 with 15 N-enriched nitric acid and nitrous acid, emission due to the nitration products o-and p-nitrophenol (2a, 2b) is observed in the 15 N-NMR spectra. The CIDNP effects are buil

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The dark reaction of NO, and HzO vapor in 1 atm of air was studied for the purpose of elucidating the recently discussed unknown radical source in smog chambers. Nitrous acid and nitric oxide were found to be formed by the reaction of NO2 and H2O in an evacuable and bakable smog chamber. No nitric a