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Acid-catalyzed rearrangement of cis-2,3-dimethylendo-2-norborneol

โœ Scribed by Hatfield, Lowell D.; Huntsman, William D.

Book ID
126271870
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
328 KB
Volume
32
Category
Article
ISSN
0022-3263

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Acid-catalyzed rearrangements of tricycl
Acid-catalyzed rearrangements of tricyclo[4.3.2]Propellane derivatives
โœ Amos B. Smith III; Barry A. Wexler ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 260 KB

The acid-catalyzed rearrangements of three model tricyclo[4.3.2] propellane derivatives have been explored. In each case the observed products are proposed to arise via a concerted 1,2-shift of the cyclobutane bond having an antiperiplanar alignment with the leaving group (i.e., stereoelectronic con