Acid-catalyzed rearrangement of abieslactone
โ Scribed by Hiroshi Irie; Shojiro Uyeo; Kaoru Kuriyama
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 176 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Reaction of linalool oxide (**1**) with acids leads to a variety of dehydration products which are shown to be aliphatic dienones and/or monocyclic enones. A mechanism is proposed to account for the generation of all these compounds.
Under acid-catalysis 7-arylbicyclo[3.2.0]hept-2-en-6-ols rearrange to diarylmethanes and cyclopenteno-annelated polycyclic aromatic hydrocarbons.
In the course of a study of the ozonoTysis of phenylcyclopropylethynyl carbinol in attempts to form phenylcyclopropylglycolic acid, a compound was isolated which was neither the anticipated product nor the starting material (1). Structure I was proposed for this anomalous product, based upon certain