𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Acid-catalyzed Rearrangements of Linalool Oxide

✍ Scribed by Ho, Tse-Lok ;Liu, Shing-Hou

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
413 KB
Volume
1983
Category
Article
ISSN
0947-3440

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Reaction of linalool oxide (1) with acids leads to a variety of dehydration products which are shown to be aliphatic dienones and/or monocyclic enones. A mechanism is proposed to account for the generation of all these compounds.

📜 SIMILAR VOLUMES

ChemInform Abstract: Acid-Catalyzed Rear
ChemInform Abstract: Acid-Catalyzed Rearrangement of Caryophyllene Oxide.
✍ W.-Y. TSUI; G. BROWN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 26 KB 👁 2 views

Acid-Catalyzed Rearrangement of Caryophyllene Oxide. -The title reaction affords besides the known clovanediol (III) epoxides (II) and (I). The structures of the latter are especially elucidated by NMR methods. Mechanisms are discussed. -(TSUI, W.-Y.;

Acid-Catalyzed Rearrangements of Vinylke
Acid-Catalyzed Rearrangements of Vinylketene/Cyclopentadiene Adducts
✍ Rima Huston; Max Rey; André S. Drieding 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 795 KB

**Säurekatalysierte Umlagerungen von Vinylketen/Cyciopentadien‐Addukten** Vier Alkyl‐vinylketene **(7b–e)**, __in situ__ durch 1,4‐Eleminierung von HCl aus den entsprechenden α,β‐ungesättigten Acylchloriden hergestellt, wurden mit Cyclopen‐tadien umgesetzt. Durch [2 + 2]‐Cycloaddition entstanden 7‐