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Acid-catalyzed Cyclization of the Ene-Product Derived from α-Pinene and PTAD

✍ Scribed by Adam, Waldemar ;Lucchi, Ottorino De ;Gillaspey, William D. ;Rosenthal, Robert J.


Publisher
Wiley (John Wiley & Sons)
Year
1984
Tongue
English
Weight
165 KB
Volume
117
Category
Article
ISSN
0009-2940

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## Abstract Acid‐catalyzed cyclization of the natural germacranolide gallicin (8) yielded, among other products, the 1,4‐epoxyeudes‐manolide 9, which has a __trans__‐fused decaline system. Under the same conditions the closely related germacranolide shonachalin A (8α‐hydroxygallicin) (3) cyclized t