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Acid-catalyzed annulation. Simple and highly stereospecific synthesis of cis-5,10-dimethyl-1(9)-octal-2-one

โœ Scribed by Zoretic, Phillip A.; Golen, James A.; Saltzman, Martin D.


Book ID
125942244
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
321 KB
Volume
46
Category
Article
ISSN
0022-3263

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Photochemical, acid, and base catalyzed
โœ D. Gravel; J. Gauthier ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 317 KB

A recent communication by Schuster and Brizzolara (1) prompts us to report our results on the investigation of the photochemical rearrangement of 5,10-dimethyl-5-hydroxy-A lV9-2-octalone (1). In studying the photochemistry of compound 1, it was hoped that the presence of a hydroxyl group in an appro