Acid-Catalyzed Rearrangement of Caryophyllene Oxide. -The title reaction affords besides the known clovanediol (III) epoxides (II) and (I). The structures of the latter are especially elucidated by NMR methods. Mechanisms are discussed. -(TSUI, W.-Y.;
โฆ LIBER โฆ
Acid-catalysed rearrangement of caryophyllene oxide
โ Scribed by Tsui, Wing-Yan; Brown, Geoffrey
- Book ID
- 125495759
- Publisher
- Royal Society of Chemistry
- Year
- 1996
- Weight
- 389 KB
- Volume
- 20
- Category
- Article
- ISSN
- 1472-7781
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## Abstract The BF~3~ ยท Et~2~Oโ and the CH~3~SO~3~Hโcatalysed rearrangements of 10 ฮฑโvinylcyclobutanones have been examined. With little acid, the ฮฒ,ฮฒโdialkyl derivatives **1** were transformed into linear dienones **2** and **3**; with more acid, they were converted into cyclopentenones **4** by _