## Abstract Die 3,5,5‐trisubstituierten 5,6‐Dihydro‐2__H__‐pyran‐2‐one **3a**‐**k** wurden durch Knoevenagel‐Reaktion in THF in Gegenwart von TiCl~4~/Pyridin synthetisiert.
Achmatowicz Approach to 5,6-Dihydro-2H-pyran-2-one Containing Natural Products
✍ Scribed by Joel M. Harris; Miaosheng Li; Jana G. Scott; George A. O'Doherty
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
## Abstract 3,5,5‐Trisubstituierte 5,6‐Dihydro‐2H‐Pyran‐2‐one **5** wurden durch Knoevenagel‐Reaktion in THF in Gegenwart von TiCl~4~/Pyridin synthetisiert.
**Synthesis of Substituted 5,6‐Dihydro‐2__H__‐pyran‐2‐ones and their Reaction with Bromine** The synthesis of the substituted 5,6‐dihydro‐2__H__‐pyran‐2‐ones **2a–f** and the reaction of **2a–e** and **1g** with bromine to **3a–f** are described.
## Abstract The ^1^H and ^13^C NMR spectra of __trans__‐ and __cis__‐__tert__‐butyl 2‐methoxy‐5,6‐dihydro‐2__H__‐pyran‐6‐carboxylates (1 and 2) and 6,6′‐disubstituted 2‐methoxy‐5,6‐dihydro‐2__H__‐pyrans (3‐7) have been recorded. HH and CH coupling constants are discussed in terms of the ^1^H~6~⇄^6^