Recently it was reported that t-butylcyanoketene <,1> possesses a high reactivity In thermal [2 + 21 cycloadditions, reacting with alkenes l-s2 amd 1,2-cyclononadiene 2. Our Interest In the synthesis of four-membered rimgs bearing bulky groups 3 as potential precursors of sterlcally hindered cyclob
Acetylenic Hydroperoxides Derived from 2e-Methyldecahydroquinolin-4-one
β Scribed by E. A. Dikusar; N. G. Kozlov; K. L. Moiseichuk
- Book ID
- 110312659
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 47 KB
- Volume
- 71
- Category
- Article
- ISSN
- 1070-3632
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Lipid hydroperoxides undergo homolytic decomposition into the bifunctional 4-hydroxy-2(E)-nonenal and 4-oxo-2(E)nonenal (ONE). These bifunctional electrophiles are highly reactive and can readily modify intracellular molecules including glutathione (GSH), deoxyribonucleic acid (DNA) and proteins. Li