Acyclic, cyclic and bicyclic olefins have been found to undergo acetylation in the gas phase under acetone chemical ionization, giving rise to diagnostic ions. Terminal olefins show enhanced loss of water from the [M + 431' adduct. The [M + 431+ ion of A3-A'-and A5-oIefins give characteristic collis
Acetone chemical ionization studies part V: Formation of (phenol + acetone)+· under chemical ionizationt
✍ Scribed by M. Vairamanp; M. S. Rajeev; G. K. Viswanadha Rao
- Book ID
- 102560149
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 188 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Acetone chemical ionization mass mass spectra of four isomeric hexenyl acetates were investigated. The characteristic decomposition of [M + CH~3~CO]^+^ adducts in the field‐free region reveals site‐specific adduct formation of acetyl ion with the double bond and the acetoxy group.
## Abstract Acetone chemical ionization mass spectra of 14 monosubstituted aromatic compounds were studied. Benzene, toluene and halobenzenes give exclusively charge‐exchange spectra with very little fragmentation. Protonation is characteristic of compounds with higher proton affinities than aceton
## Abstract Acetone chemical ionization mass spectra of acyclic, cyclic and bicyclic alkyl acetates were studied. In addition to the formation of [M + H]^+^, [M + 43]^+^ and [M + 59]^+^ ions, ions corresponding to displacement by acetone were also observed. The results suggest that the displacement
Ion-molecule reactions of four isomeric cyclopropane derivatives were investigated under chemical ionization(CI) conditions, using methane, acetone and vinyl acetate as reagent gases. The methane positiveion CI mass spectra of each of two isomer pairs 1,2 and 3,4 are identical, and so are the collis