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Acetone chemical ionization studies: Olefins

✍ Scribed by M. Vairamani; K. V. Siva Kumar; G. K. Viswanadha Rao

Book ID
102557784
Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
384 KB
Volume
25
Category
Article
ISSN
1076-5174

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✦ Synopsis

Acyclic, cyclic and bicyclic olefins have been found to undergo acetylation in the gas phase under acetone chemical ionization, giving rise to diagnostic ions. Terminal olefins show enhanced loss of water from the [M + 431' adduct. The [M + 431+ ion of A3-A'-and A5-oIefins give characteristic collision-induced dissociation spectra.

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