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Accurate measurement of tracer diffusion coefficients in aqueous solutions with sliding cell technique

โœ Scribed by Haimanti Chakrabarti; S.N. Changdar


Publisher
Elsevier Science
Year
1992
Weight
678 KB
Volume
43
Category
Article
ISSN
0883-2889

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โœฆ Synopsis


In this paper a systematic study of diffusion coefficients in liquid systems is given. The new radioactive tracer technique developed in our laboratory has been described and the experimental results in the case of several electrolyte solutions obtained by this method are described in detail. The data has been analysed in the light of the existing theories of electrolytic solutions and the phenomenological coefficients L,, , L,,, L,, have been calculated utilizing a simplified version of Onsager's theory.


๐Ÿ“œ SIMILAR VOLUMES


Determination of the diffusion coefficie
โœ A.J. van Stroe; L.J.J. Janssen ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 559 KB

AIlStraCt An accurate and rapid method for determining the diffusion coefficients of electrochemically active gases in electrolytes is described. The technique is based on chronoamperometry where transient currents are measured and interpreted with a Cottrell-related equation. The diffusion coeffici