✦ LIBER ✦

Access to Optically Active Ipsdienol from Verbenone

✍ Scribed by Günther Ohloff; Wolfgang Giersch

Book ID: 102252307
Publisher: John Wiley and Sons
Year: 1977
Tongue: German
Weight: 328 KB
Volume: 60
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19770600506

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Verbenone 1 or 2 is converted in three steps to ipsdienol 9 or 10 respectively. The diastereoisomeric 2(10)‐pinen‐4‐ols 6 and 7 (or 5 and 8), wich have identical chirality at the carbon atoms bearing OH groups, afford ipsdienol 10 (or 9 respectively) with the same optical purity as the starting material.

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