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Acceleration of the thermal pauson-khand reaction by coordinating ligands

✍ Scribed by Marie E. Kraff; Ian L. Scott; Romulo H. Romero

Book ID
104214806
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
208 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis

Khand cycloaddition. Several methods have been reported to increase the rate of the intramolecular Pauson-Khand cycloaddirion.2*3 These include performing the reaction in the presence of 4-methylmorpholine N-oxide4 or trimethylamine N-oxide' in CH.&l,, or carrying out the reaction in the dry state on silica geL6 In our earlier work' on *he ligand directed intermolecular Pauson-Khand reaction, we noted that the use of alkyl sulfides as

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