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Abstraction reactions of methylene with deuterated methyl halides

โœ Scribed by Lee, Peter S.-T.; Rowland, F. S.


Book ID
120491526
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
1001 KB
Volume
84
Category
Article
ISSN
0022-3654

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โœ A.A. Viggiano; R.A. Morris; J.F. Paulson; E.E. Ferguson ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 244 KB

The rate constants for the reactions between CD,Hf\_, and 0 have been measured and found to be fast, independent of isotope. The branching ratio for these reactions has been found to be statistical. Since decay of metastable triplet CD\*HO+ shows a large isotope effect, it was thought that the prese