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Absorption of phosphine in an aqueous solution of formaldehyde and hydrochloric acid

โœ Scribed by Raghunath V. Chaudhari; L.K. Doraiswamy


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
398 KB
Volume
29
Category
Article
ISSN
0009-2509

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โœฆ Synopsis


The absorption of phosphme m an aqueous solution of hydrochlonc acid and formaldehyde was found to be kmetlcally controlled In the range of vanables studied The reactlon was found to be first order with respect to phosphme and formaldehyde and approximately half-order with respect to hydrochlonc acid The reaction rate constants calculated were 2 34 X 10z, 5 88 X lo*, 1 84 X 103, and 4 98 x lo3 [cm3/gmole]' 5/set at 4, 13, 27 and 40ยฐC respectively and the activation energy 14740 cal/ gmole


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