An approximate model for the rate of simultaneous absorption of H2S and CO2 into aqueous solutions of a tertiary amine is presented, and the model is successfully compared with experimental results of simultaneous absorption. An effect which is not taken into account in the model is shown to become
Absorption of hydrogen sulphide by peat in the presence of ammonia
โ Scribed by Campbell, J. H. ;Skilling, W. J.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1950
- Weight
- 883 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0368-4075
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โฆ Synopsis
T h e influence of the following factors on the efficiency of peat in rcmoving hydrogen sulphide from mixtures of it with air, oxygen or nitrogen and 3 little ammonia has been investigated : ((I) variation of ammonia supplied, (b) variation of oxygen content of gas, (c) variation of moisture content of peat, (d) variation of weight of peat, (e) variation of diameter of reaction tube, (f) dilution of peat with sawdust ( ) sterilization of pent, and (11) depth of source of peat.
In a d h i k , the activities of other absorbents and of humic acids from peat have been eaaniined, and figures for the saturation of peat with sulphur have been obtained ; finally, the activity of peat and humic acids saturated with ammonia has been ascertained. A hypothesis has been submitted to explain thc cxperimcntal evidence : this suggests that the reaction is based on combination of ammonia with the humic acids in peat, followed by the decomposition of the ammonium humates with hydrogen sulphide. T h e resulting ammonium hydrogen sulphide is then oxidized to ammonia and free sulphur, and thc regcnerated ammonia is availablc for further reaction. ' B.1'. 15'3,297 . -.. 4 ~ragunov, S. s., er a/., 3. ~p p . chi. RI;SI. 193j,7, 105 attributed to the activity of bacteria, nor can the hechanism be
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