We examine the electronic spectrum of Cu(II) porphyrin using the intermediate neglect of differential overlap model. The isolated molecule is predicted to have trip-doublet absorption, corresponding to porphyrin triplets, at 9000 and 13900 cm-1. The Q band is calculated at 15900 cm-1, in good agreem
Absorption and emission properties of a europium(II) cryptate in aqueous solution
โ Scribed by N. Sabbatini; M. Ciano; S. Dellonte; A. Bonazzi; V. Balzani
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 288 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Tblhe absorptmn specuum of the complr\ bctwrcn Eu7+ and the 12.221 cryptand shows narrow. weali trammom wirhm 4f' supcrrmposed on broad, slrong lransrf~ons from 4f' to 4f65d. Emusron from 4f65d IO 41' can be obscrrcd 31 77 A (Amax = -120 nm. i = 0.55 ,,r) and 31 293 K (X,,, = -160 nm, I = 3 ns) .n aqueous saluoon.
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