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Absolute shielding scale for 31P from gas-phase NMR studies

✍ Scribed by Cynthia J. Jameson; Angel De Dios; A. Keith Jameson

Book ID: 103026118
Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 675 KB
Volume: 167
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(90)85472-o

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✦ Synopsis

Difke~~ in the "P nuclear shielding in the ztro-prcssurc limit have been measured in seven compounds. An absolute ,'P shielding scale based on the PHS molecular beam data is established and the absolute shielding of the standard liquid refercncc (85% aqueous H$Od) is found to he 328.35 ppm, based on PH, being 594.45 f 0.63 ppm. Comparisons with ab iuitio calculations show that eakulations using local origins (the IGLG method) are in good agreement with experiment.

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