Determination of 31P chemical shielding tensors from NMR studies on single crystals of chlorotris(triphenylphosphine) rhodium(I)

Determination of the Chemical Shielding

Determination of the Chemical Shielding Tensor Orientation from Two or One of the Three Conventional Rotations of a Single Crystal

✍ S.C. Shekar; A. Ramamoorthy; R.J. Wittebort 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 95 KB

Chemical shift anisotropy (CSA) is an immensely useful interaction to study the structure, dynamics, and function of a wide variety of chemical and biological molecules. Traditionally the only unambiguous way to determine both the principal values and the orientation of the principal axes of the CSA