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Absolute Rate Constants for the Reactions of Cl Atoms with a Series of Esters

โœ Scribed by Notario, Alberto; Le Bras, Georges; Mellouki, Abdelwahid


Book ID
127393154
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
76 KB
Volume
102
Category
Article
ISSN
1089-5639

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๐Ÿ“œ SIMILAR VOLUMES


Rate constants for the gas-phase reactio
โœ A. Notario; A. Mellouki; G. Le Bras ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 91 KB ๐Ÿ‘ 2 views

The laser photolysis-resonance fluorescence technique has been used to determine the absolute rate coefficient for the Cl atom reaction with a series of ethers, at room temperature (298 ฯฎ 2) K and in the pressure range 15-60 Torr. The rate coefficients obtained (in units of cm 3 molecule ฯช1 s ฯช1 ) a

Rate constants for the reactions of Cl a
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Rate constants have been measured at room temperature for the reactions of Cl atoms with formic acid and with the HOCO radical: Cl ฯฉ HCOOH !: HCl ฯฉ HOCO (R1) Cl ฯฉ HOCO !: HCl ฯฉ CO (R2) 2 Cl atoms were generated by flash photolysis of Cl 2 and the progress of reaction was followed by time-resolved i

Absolute rate constants for the reaction
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## Abstract Earlier work on the reactions of O(^3^P) atoms with HCl and HBr has been extended by measuring rate constants for equation image A flowโ€tube method was used with chemiluminescent monitoring of the removal of atomic oxygen. Rate constants were measured at temperatures between 340 and 4

Absolute rate constants for the reaction
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## Abstract A flow tube method has been used to determine rate constants for the elementary reactions: equation image Oxygen atoms were produced by adding a small excess of NO to a stream of partially dissociated nitrogen, and their reaction with hydrogen halide was monitored by observing the int