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Absolute Rate Constants for the Reaction of OH with Cyclopentane and Cycloheptane from 233 to 351 K

✍ Scribed by Gennaco, Michael A.; Huang, Yi-wen; Hannun, Reem A.; Dransfield, Timothy J.


Book ID
124169473
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
588 KB
Volume
116
Category
Article
ISSN
1089-5639

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Absolute rate constants for the reaction
✍ J. V. Michael; W. A. Payne πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 483 KB πŸ‘ 2 views

## Abstract The rate constant for the reaction of Br + O~3~ β†’ BrO + O~2~ has been measured at four temperatures from 234 to 360 K by the technique of discharge flow coupled with resonance‐fluorescence detection of bromine atoms. The measured rate constants obey the Arrhenius expression __k__ = (9.4

Absolute rate constants for the gas-phas
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The absolute rate constants for the gas-phase H-atom abstraction by hydroxyl radicals from cyclohexane and ethane have been determined at room temperature. OH radicals were produced by pulse radiolysis of an H,O-Ar mixture, and the decay of OH was followed by monitoring the transient light absorpti