Absolute Rate Constants for the Reaction of OH with Cyclopentane and Cycloheptane from 233 to 351 K
β Scribed by Gennaco, Michael A.; Huang, Yi-wen; Hannun, Reem A.; Dransfield, Timothy J.
- Book ID
- 124169473
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 588 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1089-5639
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## Abstract The rate constant for the reaction of Br + O~3~ β BrO + O~2~ has been measured at four temperatures from 234 to 360 K by the technique of discharge flow coupled with resonanceβfluorescence detection of bromine atoms. The measured rate constants obey the Arrhenius expression __k__ = (9.4
The absolute rate constants for the gas-phase H-atom abstraction by hydroxyl radicals from cyclohexane and ethane have been determined at room temperature. OH radicals were produced by pulse radiolysis of an H,O-Ar mixture, and the decay of OH was followed by monitoring the transient light absorpti