The Absolute Configuration of β-Bisabolo
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Günther Ohloff; Wolfgang Giersch; Regula Näf; François Delay
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Article
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1986
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John Wiley and Sons
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German
⚖ 326 KB
From bergamot oil (Citrus hcrgamia KISSO), (-)-(4S, 8R)-S-epi-a-bisaboloI (2) and (-)-(4R, 8S)-4-epi-p-bisa-bolo1 (3) were isolated. The absolute configuration of their stereoisomers 4 and 5 was established by an enantioselective synthesis starting from (-)-(S)-p-mentha-l,8-dien-4-ol. The bisabolol