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Absolute configuration of the substituent at C-7 in guaiol

✍ Scribed by Hitoshi Minato

Publisher: Elsevier Science
Year: 1961
Tongue: French
Weight: 214 KB
Volume: 2
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)99241-x

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✦ Synopsis

Osaka, Japan IN the preceding papers,' it was eetabliehed that both the C-4 and the C-10 methyl Bronps in guaiol (I) poeseas the a-configuration. Now the question remains as to whether the eubetituent at C-7 in guaiol is aor $-oriented. In thin rxperiment, an attempt was made to determine the absolute confiiguration of the hydroxyisopropyl group at C-7 in guaiol by degradation of l0-hydroxy-2,5-dimethyl-&!-isopropropyl-decalone-l (V) which rae reported in the previous paper. 2

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