## Abstract Polymerization of methylbutyl‐2‐(3‐thienyl)acetate (MBTA) was achieved by constant current electrolysis at low temperature. Subsequently, the syntheses of block copolymers of polyMBTA were accomplished in the presence of either pyrrole or thiophene by constant potential electrolysis. Mo
✦ LIBER ✦
Absolute Configuration and Conformational Stability of ( S )-(+)-3-(2-Methylbutyl)thiophene and (+)-3,4-Di[( S )-2-methylbutyl)]thiophene and Their Polymers
✍ Scribed by Wang, Feng; Polavarapu, Prasad L.; Lebon, France; Longhi, Giovanna; Abbate, Sergio; Catellani, Marinella
- Book ID
- 127157470
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 111 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Resolution of racemic __cis__‐3‐(2‐aminophenylthio)‐2‐hydroxy‐3‐(4‐methoxyphenyl) propionic acid (**2**) __via__ the cinchonidine salt **3**, and brucine salt **4**, isolation of the calcium salts (+)‐ and (−)‐**5**, as well as their cyclization to enantiomeric 1,5‐benzothiazepines (+)‐