✦ LIBER ✦

"Absolute" Asymmetric Synthesis Using the Chiral Crystal Environment: Photochemical Hydrogen Abstraction from Achiral Acyclic Monothioimides in the Solid State

✍ Scribed by Sakamoto, Masami; Takahashi, Masaki; Shimizu, Motoki; Fujita, Tsutomu; Nishio, Takehiko; Iida, Ikuo; Yamaguchi, Kentaro; Watanabe, Shoji

Book ID: 126948601
Publisher: American Chemical Society
Year: 1995
Tongue: English
Weight: 268 KB
Volume: 60
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00127a007

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: “Absolute” Asymmetr

ChemInform Abstract: “Absolute” Asymmetric Synthesis Using the Chiral Crystal Environment: Photochemical Hydrogen Abstraction from Achiral Acyclic Monothioimides in the Solid State.

✍ M. SAKAMOTO; M. TAKAHASHI; M. SHIMIZU; T. FUJITA; T. NISHIO; I. IIDA; K. YAMAGUC 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Solid-state photochemistry: absolute asy

Solid-state photochemistry: absolute asymmetric oxetane synthesis from an achiral acyclic imide using the chiral crystal environment

✍ Sakamoto, Masami; Takahashi, Masaki; Fujita, Tsutomu; Watanabe, Shoji; Iida, Iku 📂 Article 📅 1993 🏛 American Chemical Society 🌐 English ⚖ 228 KB

ChemInform Abstract: Spontaneous Chiral

ChemInform Abstract: Spontaneous Chiral Crystallization of Achiral Materials and Absolute Asymmetric Photochemical Transformation Using the Chiral Crystalline Environment

✍ Masami Sakamoto 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 15 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Absolute Asymmetric

ChemInform Abstract: Absolute Asymmetric Synthesis from Achiral Molecules in the Chiral Crystalline Environment

✍ M. SAKAMOTO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 23 KB 👁 2 views

Solid-State Photochemical Reaction of S-

Solid-State Photochemical Reaction of S-Phenyl-N-(benzoylformyl)thiocarbamates: "Absolute" Asymmetric Synthesis Using the Chiral Crystal Environment

✍ Sakamoto, Masami; Takahashi, Masaki; Fujita, Tsutomu; Nishio, Takehiko; Iida, Ik 📂 Article 📅 1995 🏛 American Chemical Society 🌐 English ⚖ 276 KB

Diastereo- and Enantioselective δ-H Abst

Diastereo- and Enantioselective δ-H Abstraction in the Solid State of 1-Benzoyl-8-benzylnaphthalene – Absolute Asymmetric Synthesis Due to a Chiral Crystal Environment

✍ Hermann Irngartinger; Peter Walter Fettel; Volker Siemund 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB 👁 1 views

Due to the matrix effect of the crystal lattice, irradiation of alcohol 2 could be produced, depending on which enantiomorphic form of the chiral crystal was irradiated. As ketone 1 yields 2 diastereoselectively as the main product (97% de). Furthermore, the chiral crystal environment in the ketone