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Absence of steric effects on the leaving group in SN2 reactions

✍ Scribed by Ernest L. Eliel; Rico P. Gerber

Publisher
Elsevier Science
Year
1961
Tongue
French
Weight
203 KB
Volume
2
Category
Article
ISSN
0040-4039

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A theoretical study of steric effects in
A theoretical study of steric effects in SN2 reactions
✍ Frank Jensen πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 453 KB

The gas phase reaction of chloride ion with alkyl chlorides (methyl, ethyl, propyl, i-propyl,/-butyl, t-butyl and neo-pentyl ) has been studied by ab initio methods. Geometries of stationary points along the reaction coordinate have been optimized at the MP2/6-31 G\* level of theory and improved ene